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We present a study of new 7.7–11.3 μm data obtained with theJames WebbSpace Telescope Mid-InfraRed Instrument in the starburst galaxy M 82. In particular, we focus on the dependency of the integrated CO(1–0) line intensity on the MIRI-F770W and MIRI-F1130W filter intensities to investigate the correlation between H₂content and the 7.7 and 11.3 μm features from polycyclic aromatic hydrocarbons (PAH) in M 82’s outflows. To perform our analysis, we identify CO clouds using the archival¹²CO(J = 1 − 0) NOEMA moment 0 map within 2 kpc from the center of M 82, with sizes ranging between ∼21 and 270 pc; then, we compute the CO-to-PAH relations for the 306 validated CO clouds. On average, the power-law slopes for the two relations in M 82 are lower than what is seen in local main-sequence spirals. In addition, there is a moderate correlation betweenI_{CO(1 − 0)} − I_7.7 μm/I_11.3 μmfor some of the CO cloud groups analyzed in this work. Our results suggest that the extreme conditions in M 82 translate into CO not tracing the full budget of molecular gas in smaller clouds, perhaps as a consequence of photoionization and/or emission suppression of CO molecules due to hard radiation fields from the central starburst. 

The complex physical, kinematic, and chemical properties of galaxy centres make them interesting environments to examine with molecular line emission. We present new 2 − 4″ (∼75 − 150 pc at 7.7 Mpc) observations at 2 and 3 mm covering the central 50″ (∼1.9 kpc) of the nearby double-barred spiral galaxy NGC 6946 obtained with the IRAM Plateau de Bure Interferometer. We detect spectral lines from ten molecules: CO, HCN, HCO + , HNC, CS, HC 3 N, N 2 H + , C 2 H, CH 3 OH, and H 2 CO. We complemented these with published 1 mm CO observations and 33 GHz continuum observations to explore the star formation rate surface density Σ SFR on 150 pc scales. In this paper, we analyse regions associated with the inner bar of NGC 6946 – the nuclear region (NUC), the northern (NBE), and southern inner bar end (SBE) and we focus on short-spacing corrected bulk (CO) and dense gas tracers (HCN, HCO + , and HNC). We find that HCO + correlates best with Σ SFR , but the dense gas fraction ( f dense ) and star formation efficiency of the dense gas (SFE dense ) fits show different behaviours than expected from large-scale disc observations. The SBE has a higher Σ SFR , f dense , and shocked gas fraction than the NBE. We examine line ratio diagnostics and find a higher CO(2−1)/CO(1−0) ratio towards NBE than for the NUC. Moreover, comparison with existing extragalactic datasets suggests that using the HCN/HNC ratio to probe kinetic temperatures is not suitable on kiloparsec and sub-kiloparsec scales in extragalactic regions. Lastly, our study shows that the HCO + /HCN ratio might not be a unique indicator to diagnose AGN activity in galaxies.